I am having the same problem, with 2 different sites. It seems to work fine in Firefox, but when I download an attachment, it adds ".zip" to the end of the file. Here is an example:
www.lovetoteach.org/resources/reward-coupons.html
In Firefox, you will get caught_being_good_fish.pdf
In Chrome, you will get caught_being_good_fish.pdf.zip
WIth Chrome, you need to remove the ".zip" from the end of the file name, and then it opens fine.
Any ideas?